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我国部分南极陨石的分类和宇宙成因核素10Be和26Al的研究
其他题名Classification and study of cosmogenic 10Be and 26Al of Antarctic meteorites collected from Grove Mountains region
卢仁
2008-05-30
学位授予单位中国科学院地球化学研究所
学位授予地点地球化学研究所
学位名称博士
关键词陨石 化学分离纯化 宇宙成因核素10be和26al 暴露年龄 居地年龄
摘要随着我国南极陨石的大量回收,对陨石的研究也越来越深入。本文主要对我国部分南极陨石和沙漠陨石开展了三方面的工作:(1)我国部分南极陨石的分类;(2)陨石中宇宙成因核素10Be和26Al的化学分离、纯化实验;(3)我国部分南极陨石和沙漠陨石的全岩化学组成分析和宇宙成因核素10Be和26Al的初步研究。 1、我国部分南极陨石的分类研究 通过对我国19次南极科考队回收的4448块陨石中24块南极普通球粒陨石的矿物、岩石分析,将这24块陨石化学-岩石类型进行了划分,分别为1个H3型(GRV 021603)、2个H4型(GRV 020200和GRV 021493)、4个H5型(GRV 020048、GRV 020078、GRV 020129和GRV 020236)、2个H6型(GRV 020075和GRV 020226)、1个L4型(GRV 021563)、8个L5型(GRV 020047、GRV 020283、GRV 020297、GRV 021547、GRV 021547、GRV 021581、GRV 021615和GRV 023771)、5个L6型(GRV 020103、GRV 020155、GRV 021505、GRV 021711和GRV 022171)、1个LL4型(GRV 020029)和1个LL6型(GRV 021496)。在此基础上,将我国的南极陨石和美国的南极陨石进行了类型和质量分布模型的对比。结果表明,我国南极陨石比美国南极陨石具有相对高的L群丰度;我国的南极陨石质量分布模型与美国南极陨石一致。 2、陨石中宇宙成因核素10Be和26Al的化学分离、纯化实验 在前人关于陨石中宇宙成因核素10Be和26Al的分离方法基础上,通过多次模拟样品的分离实验,成功地将陨石中Be和Al进行了分离、纯化。并且进一步改善了前人的分离方法,将Be的淋洗液由原来的120ml减少为90ml。在此基础上,用空白样品和吉林陨石的硅酸盐样品对整个化学分离实验进行了检验,并将所获得的BeO和Al2O3粉末用加速器质谱(AMS)进行了10Be和26Al的测试。根据所测定的10Be和26Al数据,计算得到吉林陨石的暴露年龄为0.52Ma,这一结果与前人所获得的吉林陨石第二阶段的暴露年龄0.4Ma接近。这一结果再次证明了陨石中宇宙成因核素10Be和26Al的分离流程是成功的,同时也说明本次所测的吉林陨石样品为吉林陨石第二阶段暴露辐射的样品。 3、我国部分南极陨石和沙漠陨石的全岩化学组成分析以及宇宙成因核素10Be和26Al的初步研究 对我国13块南极陨石和3块沙漠陨石进行了全岩化学成分的分析,其结果进一步证明了这些陨石由岩石、矿物分析所划分的类型的正确性。在这些陨石类型和全岩分析的基础上,对它们进行了宇宙成因核素10Be和26Al的初步分析。得到其中4块南极陨石和2块沙漠陨石的暴露年龄和居地年龄,这些陨石暴露年龄的范围为2.09-3.05Ma,居地年龄为0-0.23Ma。
其他摘要Recently, the researches of meteorites are becoming more thoroughly and extensively as great numbers of meteorites were collected in Antarctica and hot desert. There are three parts in this dissertation about partial Antarctic meteorites and desert meteorites of China: 1) Classification of some meteorites in Antarctic Grove Mountains (GRV); 2) Experiment research on chemical separation and purification of cosmogenic radionuclides 10Be and 26Al in meteorites, and 3) Research on bulk compositions and cosmogenic radionuclides 10Be and 26Al in some Antarctic meteorites and desert meteorites of China. 1) Classification of some GRV meteorites Petrography and mineral chemistry of 24 ordinary chondrites from the Grove Mountain, Antarctic, have been studied to identify their chemical-petrographic types. These meteorites samples were selected from a total of 4448 Grove Mountain meteorites collected during the 19th Chinese Antarctic Research Expedition. The chemical-petrographic types of these meteorites are: 1 H3 (GRV 021603), 2 H4 (GRV 020200 and GRV 021493), 4 H5 (GRV 020048, GRV 020078, GRV 020129 and GRV 020236), 2 H6 (GRV 020075 and GRV 020226), 1 L4 (GRV 021563), 8 L5 (GRV 020047, GRV 020283, GRV 020297, GRV 021547, GRV 021547, GRV 021581, GRV 021615 and GRV 023771), 5 L6 (GRV 020103, GRV 020155, GRV 021505, GRV 021711 and GRV 022171), 1 LL4 (GRV 020029) and 1 LL6 (GRV 021496). The comparison of chemical-petrographic types and mass distribution models on Antarctic GRV meteorites collected by Chinese researchers and US researchers was completed. It has shown that the Antarctic GRV meteorites have higher abundance of L group, and all of these samples have almost same mass distribution model. 2) Experiments of chemical separation and purification of cosmogenic radionuclides 10Be and 26Al in meteorites According to the existed methods of chemical separation and purification of cosmogenic radionuclides in meteorites, 10Be and 26Al have been separated and purified successively by us with several experiments. The experiment methods have been advantaged, the volume of Be solution was changed from 120ml to 90ml. The blank sample and one Jilin meteorite were employed to verify the entire experiment process, the abundance of 10Be and 26Al were analyzed by accelerator mass spectrometry (AMS). The exposure age of Jilin meteorite in this experiment is 0.52Ma, which is in agreement with the published exposure age 0.4Ma of the second stage of Jilin meteorites. It approved that the experiment of chemical separation of cosmogenic radionuclides 10Be and 26Al is successful, as well as show the Jilin meteorite sample in this study belong to a second-exposure stage sample. 3) Researches on bulk composition and cosmogenic radionuclides 10Be and 26Al in some Antarctic meteorites and desert meteorites of China 13 GRV meteorites and 3 desert meteorites were analyzed in order to achieve their bulk compositions. The chemical analysis results have proved their classification of petrography and mineralogy is correct. The terrestrial age and exposure age of 4 GRV meteorites and 2 desert meteorites were estimated based on the experiment results of cosmogenic radionuclides 10Be and 26Al. The terrestrial age ranges from 0 - 0.23Ma, and exposure age from 2.09 - 3.04Ma.
页数95
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/3266
专题研究生_研究生_学位论文
推荐引用方式
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卢仁. 我国部分南极陨石的分类和宇宙成因核素10Be和26Al的研究[D]. 地球化学研究所. 中国科学院地球化学研究所,2008.
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