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Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress
Qingyou Liu; Heping Li
2011
Source PublicationInternational Journal of Mineral Processing
Volume98Issue:1-2Pages:82-88
AbstractThe electrochemical behaviour of chalcopyrite (CuFeS2) was studied by polarisation curve and electrochemical impedance spectroscopy (EIS) in FeCl3 solution at room temperature under differential stress. Experimental results showed the relation between chalcopyrite potential difference and elastic stress is ΔφCuFeS2 H = − VdP ZF . The corrosion current density and charge transfer electrical resistance increased distinctly, whereas double-layer capacitance decreased and the corrosion potential became more negative with increasing differential stress. The EIS data have been analyzed and discussed in the simple equivalent circuit model, the Randles equivalent electrical circuit model and the point defect model, respectively. The experimental results are significant for mineral processing and hydrometallurgy.
KeywordChalcopyrite Polarisation Curves Electrical Impedance Spectroscopy Differential Stress
Subject Area地球深部物质与流体作用地球化学
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/352002/7021
Collection地球内部物质高温高压实验室_地球内部物质高温高压实验室_期刊论文
Recommended Citation
GB/T 7714
Qingyou Liu,Heping Li. Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress[J]. International Journal of Mineral Processing,2011,98(1-2):82-88.
APA Qingyou Liu,&Heping Li.(2011).Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress.International Journal of Mineral Processing,98(1-2),82-88.
MLA Qingyou Liu,et al."Electrochemical behaviour of chalcopyrite (CuFeS2) in FeCl3 solution at room temperature under differential stress".International Journal of Mineral Processing 98.1-2(2011):82-88.
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